Metal-free cascade radical cyclization of 1,6-enynes with aldehydes.
نویسندگان
چکیده
A new and efficient metal-free cascade cyclization of 1,6-enynes with aldehydes is developed for the synthesis of tricyclic fluorene derivatives. The reaction involves a radical process and one C(sp(2))-C(sp(2)) and two C(sp(2))-C(sp(3)) bonds are formed simultaneously in one pot by using PivOH and TBHP.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 50 13 شماره
صفحات -
تاریخ انتشار 2014